Product ID:CALUMET 142 FLASH NAPTHA RULE 66, 0420-00
MSDS Date:03/24/1997
FSC:6810
NIIN:00-201-1316
Status Code:A
MSDS Number: CKRDV

Emergency Phone: 318-949-2421

Info Phone: 318-949-2421

Preparer: JENNIFER HALL

Cage: EO350

Telephone: 800-284-5279

Cage: 1ELU0

HYDROTREATED LIGHT DISTILLATE (PETROLEUM)

CAS: 64742-47-8

RTECS: OA5504000

ACGIH TLV: 100 PPM

LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: SOME IRRITATION. SKIN: SLIGHT
IRRITATION UPON SHORT-TERM EXPOSURE AND DERMATITIS ON PROLONGED
CONTACT. INGESTION: ACUTE ASPIRATION HAZARD. PNEUMONITIS, PULMONARY
ADEMA, CENTRAL NERVOUS SYSTEM DE PRESSION. INHALATION: NASAL AND
RESPIRATORY IRRITATION, CENTRAL NERVOUS SYSTEM DEPRESSION. CHRONIC:
PROLONGED AND/OR REPEATED CONTACT WITH THIS MATERIAL MAY PRODUCE
SKIN AND EYE IRRITATION.
Explanation of Carcinogenicity:THIS PRODUCT DOES NOT REQUIRE A CANCER
HAZARD WARNING IN ACCORDANCE WITH THE OSHA HAZARD COMMUNICATION
STANDARD.
Effects of Overexposure:SLIGHT IRRITATION, HEADACHE, NAUSEA,
DROWSINESS, FATIGUE, PNEUMONITIS, PULMONARY ADEMA, CENTRAL NERVOUS
SYSTEM DEPRESSION, CONVULSIONS, LOSS OF CONSCIOUSNESS, NASAL AND
RESPIRATORY IRRITATION, BREATHL ESSNESS, .
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS SHOULD AVOID CONTACT WITH THIS PRODUCT. SENSITIVE SKIN
AND DERMATITIS.

First Aid:EYES: FLUSH EYES IMMEDIATELY WITH WATER A MINIMUM OF 15 MIN
OCCASIONALLY LIFTING LOWER AND UPPER LIDS. IF IRRITATION PERSISTS,
GET MEDICAL ATTENTION PROMPTLY. SKIN: WASH SKIN THOROUGHLY WITH
SOAP & WA TER. IMMEDIATELY REMOVE CONTAMINATED CLOTHING & LAUNDER
BEFORE REUSE. IF IRRITATION OR RASH DEVELOPS, OBTAIN MEDICAL
ASSISTANCE. INGESTION: CALL A PHYSICIAN IMMEDIATELY. DO NOT INDUCE
VOMITING EXCEPT AT THE INSTRUCTION OF A PHYSICIAN. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE
PATIENT TO FRESH AIR & CONSULT A PHYSICIAN. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION.

Flash Point Method:TCC
Flash Point:>61.1C, 142.F
Autoignition Temp:>315.6C, 600.F
Lower Limits:0.7% (EST)
Upper Limits:6% (EST)
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, AND FOAM. CAUTION:
WATER STREAM MAY SPREAD FIRE.
Fire Fighting Procedures:USE WATER SPRAY ONLY TO COOL CONTAINERS
EXPOSED TO FLAMES. DO NOT ENTER ENCLOSED OR A CONFINED WORK SPACE
WITHOUT PROPER PROTECTIVE EQUIPMENT. FIRE FIGHTING PERSONNEL SHOULD
WEAR RESPIRATORY PROTECTIO N (POSITIVE PRESSURE IF AVAILABLE). IF
LEAK OR SPILL HAS NOT IGNITED, USE WATER SPRAY TO DISPERSE THE
VAPORS.
Unusual Fire/Explosion Hazard:CAN FORM FLAMMABLE MIXTURES WITH AIR AND
FLASH AT ROOM TEMPERATURE. EXPLOSION HAZARD IN FIRE SITUATION.
VAPOR HEAVIER THAN AIR AND MAY TRAVEL CONSIDERABLE DISTANCE TO A
SOURCE OF IGNITION AND FLASH BA CK.

Spill Release Procedures:NOTIFY EMERGENCY RESPONSE PERSONNEL. EVACUATE
AREA AND REMOVE IGNITION SOURCES. BUILD DIKE TO CONTAIN FLOW.
REMOVE FREE LIQUID. SHUT OFF IGNITION SOURCE. CONTAIN SPILL AND
KEEP FROM ENTERING WATERWAYS OR SEWER. USE PERSONAL PROTECTIVE
EQUIPMENT. ADVISE EPA; STATE AGENCY IF REQUIRED. ABSORB ON INERT
MATERIAL. SHOVEL, SWEEP OR VACUUM SPILL AND PLACE IN CLOSED
CONTAINER FOR DISPOSAL.
Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY.

Handling and Storage Precautions:STORE AS OSHA CLASS IIIA COMBUSTIBLE
LIQUID. KEEP AWAY FROM FLAMES, SPARKS OR HOT SURFACES. NEVER USE A
TORCH TO CUT OR WELD ON OR NEAR CONTAINER. EMPTY OIL CONTAINERS CAN
CONTAIN EXPLOSIVE VAPORS. WA SH THOROUGHLY AFTER HANDLING. DO NOT
STORE WITH STRONG OXIDIZERS.
Other Precautions:EMPTY CONTAINERS RETAIN PRODUCT RESIDUE (LIQUID AND
VAPOR) AND CAN BE DANGEROUS.

Respiratory Protection:PETROLEUM DISTILATES (NAPHTHA).. UP TO 100PPM,
HALF MASK ORGANIC VAPOR RESPIRATOR. UP TO 5,000PPM, FULL FACE
ORGANIC VAPOR RESPIRATOR OR FULL FACE SUPPLIED AIR RESPIRATOR.
GREATER THAN 5,000PPM, FIRE FIGHING, OR UNKNOWN CONCENTRATION,
SELF CONTAINED BREATHING APPARATUS WITH POSITIVE PRESSURE.
Ventilation:USE ADEQUATE VENTILATION TO KEEP OIL MISTS OF THIS MATERIAL
BELOW APPLICABLE STANDARD(S).
Protective Gloves:WEAR PROTECTIVE IMPERVIOUS GLOVES - NEOPRENE,
NITRILE, VITON.
Eye Protection:SAFETY GLASSES, SPLASH GOGGLES, OR FACE SHIELD.
Other Protective Equipment:HAVE SUITABLE EYE WATER WASH AVAILABLE. IF
PROLONGED CONTACT CANNOT BE AVOIDED WEAR IMPERVIOUS GLOVES AND
CLOTHING. IF THERE IS A LIKELIHOOD OF SPLASHING OIL RESISTANT
CLOTHING SHOULD BE WORN.
Work Hygienic Practices:NEVER WEAR SOAKED CLOTHING. LAUNDER OR DRY
CLEAN BEFORE WEARING. DISCARD OIL SOAKED SHOES. AFFIX WARNING
LABELS ON CONTAINERS IN ACCORDANCE WITH 29 CFR 1910.1200 (HAZARD
COMMUNICATION STANDARD).
Supplemental Safety and Health
MAINTAIN LOCAL OR DILUTION VENTILATION TO KEEP CONTRATION IN AIR LOW.
LOADING, UNLOADING, TANK GAUGING, ETC., REMAIN UPWIND. REQUEST
ASSISTANCE OF SAFETY AND INDUSTRIAL HYGIENE PERSONNEL TO DETERMINE
AIR CONCENTRATIONS.

HCC:V4
Boiling Pt:>180.C, 356.F
B.P. Text:IBP
Vapor Pres:1MMHG @ 100F
Vapor Density:6 (AIR=1)
Volatile Org Content %:99
Spec Gravity:0.77 (WATER=1)
pH:NEUTRAL
Viscosity:1.3 CST @ 100F
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Solubility in Water:NEGLIGIBLE IN WATER
Appearance and Odor:CLEAR LIQUID; KEROSINE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:SOURCES OF IGNITION.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION MAY PRODUCE
CARBON MONOXIDE AND OTHER ASPHYXIANTS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:FOLLOW FEDERAL, STATE AND LOCAL REGULATIONS. IF
"USED", RCRA CRITERIA MUST BE DETERMINED. DO NOT FLUSH TO
DRAIN/STORM SEWER. CONTACT TO AUTHORIZED DISPOSAL SERVICE. IF
PERMITTED, INCINERATION MAY BE P RACTICAL. RECOMMEND RECYLING.

Toxicological Information:ACUTE: EYE EFFECTS: SLIGHT IRRITATION ON
CONTACT. SKIN EFFECTS: MAY CAUSE IRRITATION OR DERMATITIS WITH
PROLONGED & REPEATED CONTACT. ACUTE ORAL EFFECTS: TESTS OON SIMILAR
MATERIALS INDICATE AN ORDER OF ACUTE ORAL TOXICITY. ACUTE
INHALATION EFFECTS: ACUTE TOXICITY EXPECTED ON INHALATION. MEDICAL
CONDITIONS AGGRAVATED BY OVEREXPOSURE: DERMATITIS AND SENSITIVE
SKIN. NOTE: THIS PRODUCT IS NOT LISTED AS CARCINOGENIC OR A
POTENTIAL CARCINOGEN BY NTP, IARC OR OSAH. NEVERTHELESS, GOOD
INDUSTRIAL HYGIENE PRACTICES ARE RECOMMENDED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA GIVEN.

Transport Information:PROPER SHIPPING NAME: COMBUSTIBLE LIQUID, N.O.S.
(PETROLEUM NAPHTAH SOLVENT), NA1993, PGIII. HAZARD CLASS:
COMBUSTIBLE LIQUID. DOT IDENTIFICATION NUMBER: NA1993. DOT SHIPPING
LABEL: NONE REQUIRED. DLA -HMIS NOTE: SINCE THIS IS RATED A
DOT-COMBUSTIBLE BY THE MANUFACTURER, ONLY BULK SHIPMENTS
(CONTAINERS OVER 199 GALLONS) ARE REGULATED (49 CFR 173.150 (F)
(2)).

SARA Title III Information:SARA TITLE III HAZARD CLASSES: FIRE HAZARD.
SARA TITLE III - SECTION 313 SUPPLIER NOTIFICATION: NOT AVAILABLE
AT DATE OF REVISION. SARA 302 TPQ: NOT APPLICABLE. SARA 304 RQ: NOT
APPLICABLE. SARA 311 C ATAGORIES: IMMEDIATE (ACUTE) HEALTH EFFECTS:
NO; DELAYED (CHRONIC) HEALTH EFFECTS: NO; FIRE HAZARD: NO; SUDDEN
RELEASE OF PRESSURE HAZARD: NO; REACTIVITY HAZARD: NO.
Federal Regulatory Information:EPA/TSCA INVENTORY: THE COMPONENTS OF
THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICALS.
CERCLA: NO CHEMICALS IN THIS PRODUCT ARE SUBJECT TO THE REPORTING
REQUIREMENTS OF CERCLA.
State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.